Anion-π and Cation-π Interactions on the Same Surface
نویسندگان
چکیده
منابع مشابه
Additivity of Cation-π Interactions: An ab Initio Computational Study on π-Cation-π Sandwich Complexes
Center for Drug DiscoVery and Design, State Key Laboratory of New Drug Research, Shanghai Institute of Materia Medica, Shanghai Institutes of Biological Sciences, Chinese Academy of Sciences, 555 Zu Chong Zhi Road, Shanghai, 201203, P. R. China, Technology Centre for Life Sciences, Singapore Polytechnic, 500 DoVer Road, Singapore 139651, Department of Neurobiology, Weizmann Institute of Science...
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Five 8-(4-R-phenyl)-1-naphthol derivatives were prepared by PdCl(2)-catalysed electrophilic aromatic substitution. The pK(a)' values for these 1,8-disubstituted arene naphthols have been measured in acetonitrile/water (R = NO(2), 8.42; R = Cl, 8.52; R = H, 8.56; R = Me 8.68; and R = OMe, 8.71) and indicate a correlation with the electronic nature of the arene substituent, as determined through ...
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2014
ISSN: 0044-8249
DOI: 10.1002/ange.201407161